期刊
TETRAHEDRON LETTERS
卷 46, 期 14, 页码 2423-2426出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.02.054
关键词
Suzuki; heterocycles; bis(indole); dragmacidin; palladium
A facile formal total synthesis of dragmacidin B, trans-dragmacidin C, and cis- and trans-dihydrohamacanthins A is presented. Our approach to these bis(indole) alkaloids involves a one-pot, four-step cross-coupling/deprotection sequence where complete halogen selectivity is observed. A related approach to access the dihydrohamacanthins is also described. (c) 2005 Elsevier Ltd. All rights reserved.
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