期刊
SYNLETT
卷 -, 期 6, 页码 879-891出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2005-864832
关键词
calixnaphthalenes; calixarenes; naphthalene; formaldehyde; 1-naphthol; 1-naphthol; 2,3-dihydroxynaphthalene; supramolecular complexes; host-guest complexes; fullerenes
The first naphthalene ring-based analogues of the better-known and extensively studied calixarenes were synthesized in 1993. Since that time, our group has focused its research on the design and synthesis of other 'calixnaphthalenes'. These endeavours are motivated partly due to the synthetic challenges which they provide, and to the challenge, in deciphering their structural and complexation properties. Calixnaphthalenes offer several advantages over their calixarene analogues. Among these are the facts that they can form deeper, more electron-rich and in some cases, chiral, cavities. They also provide a wide range of potential new scaffolds upon which to design and build new receptors for neutral, or charged guest species. Their supramolecular complexation properties have barely been explored as yet since in most cases, only relatively small quantities only of these compounds have been obtained. In this review, all of the known, and previously unreported calixnaphthalenes are described. As well, some of the compounds, which are described, are still subjects of ongoing research.
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