期刊
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
卷 38, 期 7, 页码 853-866出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/38/7/007
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We present a fully exact non-relativistic calculation of the energies and wavefunctions of the J = I states of the HD+ molecular ion. The energies are obtained with a very high accuracy of 10(-14) au, representing, for most levels, an improvement by several orders of magnitude over previous calculations. We compute the static polarizabilities of the J = 0 states, which are in agreement with the literature, with an improved accuracy, as well as the two-photon transition probabilities and light shifts between J = 0 states. Finally, we extend our study to transitions between higher J states, using an approximate expression of the transition probability, and discuss the feasibility of a two-photon spectroscopy experiment in HD+.
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