The (B) over tilde (1A)(1) (state of SiH)(2) (and SiD)(2) (was observed by the optical-optical double resonance technique for the first time. The electronic band origin of the (B) over tilde state of SiD)(2) (was determined to be 27 214.11 cm-1. A very clear exclusive behavior depending on the even/odd value of the bending vibrational quantum Dumber was observed in the spectra, representing a quasilinear behavior of the (B) over tilde state. The barrier height to linearity was estimated to be ~ 125 cm-1 by the quasilinear analysis of the bending vibrational level structure of SiD)(2). 2005 American Institute of Physics.
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