期刊
BIOORGANIC & MEDICINAL CHEMISTRY
卷 13, 期 8, 页码 2901-2905出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.bmc.2005.02.012
关键词
alcohol; oxidation; supported; metalloporphyrin
Mild and efficient oxidation of primary and secondary alcohols with sodium periodate catalyzed by Mn(TPyP), [manganese(III)tetra(4-pyridyl)porphyrin], supported on chloromethylated polystyrene, [Mn(TPyP)-CMP], at room temperature were reported. This catalyst can be reused consecutively four times in the oxidation of 4-chlorobenzyl alcohol in 97% yield without significant loss of its activity. (c) 2005 Elsevier Ltd. All rights reserved.
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