期刊
SYNTHESIS-STUTTGART
卷 -, 期 6, 页码 957-960出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2005-861796
关键词
asymmetric catalysis; 1,3-diketones; aminations; amines; chiral Lewis acids
The direct asymmetric amination of 1,3-diketones by azodicarboxylates catalyzed by chiral copper(II) bisoxazolines is presented. Screening of chiral bisoxazoline ligands, Lewis acids, solvents, and other reaction parameters led to an enantioselective direct amination in the 2-position of 1,3-diketones and the optically active functionalized molecules were obtained in high yields and enantioselectivities.
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