期刊
INORGANIC CHEMISTRY
卷 44, 期 8, 页码 2573-2575出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic050047r
关键词
-
资金
- NIEHS NIH HHS [S11 ES011181] Funding Source: Medline
- NIGMS NIH HHS [R25 GM061347] Funding Source: Medline
The disulfonamide ligands 1,2-C6H4(NH2SO2C6H5)(2) (1) and 1,2-C6H4(NH2SO2C6H4-p-Bu')(2) (2), which are readily available in good yields from o-phenylenediamine and the corresponding sulfonyl chlorides, efficiently extract Pb(II) from water into 1,2-dichloroethane when used in synergistic combinations with 2,2'-bipyridine via an ion-exchange mechanism. The extraction was shown to proceed via the formation of a ternary Pb-sulfamido-2,2'-bipyridine complex. The X-ray crystal structure of the binary Pb-sulfamido complex 3 shows a coordination polymer with a stereochemically active lone pair on Pb formed by S=O-Pb axial coordination.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据