期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 26, 期 8, 页码 626-631出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200400644
关键词
epoxy; living polymerization; poly(epsilon-caprolactone); ring-opening polymerization; titanium
The (TiCp2Cl)-Cp-III-catalyzed radical ring opening of epoxides produces Ti alkoxides which initiate the ring-opening polymerization of epsilon-caprolactone. A linear dependence of (M) over bar on conversion, linear kinetics, low (M) over bar (w)(M) over bar (n) values, and the synthesis of block copolymers demonstrate a living process, while NMR spectroscopy confirms the presence of the initiator chain end. Epoxides are thus introduced as a new class of initiators for the Ti-catalyzed living ring-opening polymerization of cyclic esters.
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