期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 690, 期 9, 页码 2376-2380出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.02.014
关键词
ethynylated compound; Pt(II); cyclic voltammetry; X-ray structure
The electrochemical study on Pt(II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans[Pt(C C-C6H4NO2)(2)(PPh3)(2)] is showed. (c) 2005 Elsevier B.V. All rights reserved.
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