期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 6, 页码 811-815出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404383
关键词
azides; cycloaddition; kinetics; mechanism; nanoclusters; triple bonds
Air-stable copper nanoclusters are good catalysts in the Cu(I)-catalysed click cycloaddition of azides with terminal alkynes to give 1,4-disubstituted 1,2,3-triazoles. No additional base or reducing agent is required. The reaction kinetics using various copper catalyst types and the function of copper particles in this system are studied and discussed.
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