TPR, TPO, and TPD examinations of Cu0.15Ce0.85O2-y mixed oxides prepared by co-precipitation, by the sol-gel peroxide route, and by citric acid-assisted synthesis

Temperature-programmed reduction (TPR), oxidation (TPO), and desorption (TPD) studies were performed on three copper-ceria mixed oxide samples having the same nominal composition, Cu0.15Ce0.85O2-y, but prepared in three different ways: by co-precipitation, the sol-gel peroxide route, and the sol-gel citric acid route. The obtained results reveal that despite a drastic initial drop in specific surface area after consecutive redox cycles, the hydrogen consumption remains constant. This is because CuO is highly dispersed over the surface of CeO2 nanocrystallites and remains highly dispersed even after the agglomeration of CeO2 nanocrystallites in a denser secondary structure. The dispersed CuO is reduced to Cu-0 during the TPR, forming agglomerated metal particles on the surface of partially reduced CeO2. However, after subsequent temperature-programmed oxidation all the Cu-0 is oxidized back into CuO and redispersed over the CeO2 crystallites. (c) 2004 Elsevier Inc. All rights reserved.