期刊
ADVANCED MATERIALS
卷 17, 期 9, 页码 1162-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200402073
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Nanoporous thin polymer films have been produced by a simple two-step approach using metallo-supramolecular block copolymers as the starting materials. The first step is the self-assembly of the copolymer, yielding cylindrical microdomains oriented normal to the substrate. The second step involves the opening of the metal-ligand complex located at the junction of the two blocks by redox chemistry to release the minor block and create the pores (see Figure).
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