Single-crystalline gold nanorods have been prepared by one-step, seedless solvothermal reduction of HAuCl4 center dot 4H(2)O in cetyltrimethylammonium bromide (CTAB)/octane + butanol/formamide microemulsions. Formamide provides not only reduction but also sites occupied by Au3+ ion through replacing water pools in the traditional microemulsions.
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