Carbon nanofiber supported Ni catalyst:: Effects of nanostructure of supports and catalyst preparation

Carbon nanofibers (CNFs) have been used as templates for manipulating the properties of Ni catalyst particles. Both incipient wetness impregnation and deposition-precipitation have been used to prepare the catalysts. Relatively well-dispersed Ni nanoparticles have been prepared on oxidised CNFs by incipient wetness impregnation. The diameter of the CNFs has been shown to have a significant effect in determining the Ni crystal size. In addition, CNFs are suitable templates to induce microstrain to metal particles. Such microstrain has significant effects on the activity of Ni crystals during ethane hydrogenolysis. This provides new opportunities to manipulate the crystal size and activity of the metal by selecting proper carbon nanofibers as support. TPO has been demonstrated as a powerful tool to study the CNF supported catalyst and to provide information on Ni loading and relative activity of NiO for CNF oxidation. (c) 2005 Elsevier B.V. All rights reserved.