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Temperature dependence of homogeneous nucleation rates for water: Near equivalence of the empirical fit of Wolk and Strey, and the scaled nucleation model

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JOURNAL OF CHEMICAL PHYSICS
卷 122, 期 20, 页码 -

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AMER INST PHYSICS
DOI: 10.1063/1.1906213

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It is pointed out that the temperature fitting function of Wolk and Strey [J. Phys. Chem. 105, 11683 (2001)], recently shown to convert the Becker-Doring [Ann. Phys. (Leipzig) 24, 719 (1935)] nucleation rate into an expression in agreement with much of the experimental water nucleation rate data, also converts the Becker-Doring rate into a form nearly equivalent with the scaled nucleation rate model, J(scaled)=J(oc) exp[-16 pi Omega(3)(T-c/T-1)(3)/3(ln S)(2)]. In the latter expression J(oc) is the inverse thermal wavelength cubed/sec, evaluated at T-c. (c) 2005 American Institute of Physics.

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