期刊
ORGANIC LETTERS
卷 7, 期 11, 页码 2289-2291出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol050768u
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资金
- NCI NIH HHS [NIH CA91904] Funding Source: Medline
The synthesis of a hetero-bis-metallo 1,3-butadiene is reported, and its use as an orthogonal Stille and Suzuki-Miyaura coupling partner is detailed. The tin/boron diene participated successfully in a one-pot, sequential Stille and Suzuki-Miyaura coupling protocol, and its utility was demonstrated in the two-step construction of the pentaene side chain of the Fusarium metabolite lucilactaene.
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