期刊
APPLIED ENERGY
卷 113, 期 -, 页码 59-66出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.apenergy.2013.07.007
关键词
Cross-linking; Shape-stabilized phase change materials; Color matching; Broadband visible light-harvesting; Light-to-heat conversion
资金
- National Natural Science Foundation of China [21276042]
- National Science and Technology Pillar Program [2013BAF08B06]
- Jiaogai Foundation of DUT [JGXM201224]
- Fundamental Research Funds for the Central Universities of China [DUT13LK35]
Broadband visible sunlight usage and shape-stabilized effect were achieved using organic, cross-linking, and shape-stabilized phase-changed materials (OCSPCMs) with broadband visible light absorption, which were obtained by cross-linking reticulation and color matching (yellow, red, and blue) according to solar irradiation energy density. The obtained OCSPCMs exhibited excellent form-stable phase-change energy storage and broadband visible light-harvesting. Under broadband irradiation (from 400 nm to 700 nm), the light-to-heat conversion and the thermal energy storage efficiency (n > 0.74) of the OCSPCMs were significantly improved upon solar irradiation by color matching compared with those of OCSPCMs with single-band selective absorption of visible light (yellow, red, or blue). Differential scanning calorimetric results indicated that the phase change temperatures and latent heats of OCSPCMs ranged from 32.6 degrees C to 60.2 degrees C and from 120.1 J/g to 132.7 J/g, respectively. The novel materials show a reversible (more than 200 cycles) phase transition via ON/OFF switching of visible light irradiation. (C) 2013 Published by Elsevier Ltd.
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