期刊
JOURNAL OF POWER SOURCES
卷 144, 期 1, 页码 238-243出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2004.12.043
关键词
PVdF-HFP copolymer; polymer electrolytes; thermal shutdown; cross-linking; mechanical property
PVdF-HFP (polyvinylidenefluoride-hexafluoropropylene) polymer electrolytes comprising cross-linkable PEGDMA (polyethylene glycol dimethacrylate) oligomers with thermal shutdown characteristic have been developed. In contrast to the melting mechanism of polyolefin, this new polymer electrolyte possesses a thermal shutdown characteristic by a rapid cross-linking reaction of PEGDMA. The cross-linked PEGDMA network inside the PVdF-HFP matrix can provide the mechanical strength for the electrolytes, while the un-cross-linked PEGDMA oligomers serve as plasticizers for PVdF-HFP to improve the mobility of lithium ions at normal operation temperatures. In addition, the un-cross-linked PEGDMA oligomers can initiate cross-linking upon a sudden rise of temperature and thus provide thermal shutdown protection at elevated temperatures. (c) 2005 Elsevier B.V. All rights reserved.
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