期刊
THIN SOLID FILMS
卷 480, 期 -, 页码 486-490出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2004.11.007
关键词
Cu(In,Ga)Se-2; selenium vapour; auger electron spectroscopy
A simple process for the deposition of Cu(In,Ga)Se-2 (CIGS) absorber layers is described. A low-cost CIGS precursor paste deposited by simple and fast doctor blade technique is subsequently selenized under selenium vapour in a quartz tube at 10 mbar (10 min at 550 C). The precursor paste is prepared with metal chlorides and nitrates dissolved in alcohol. The solution is then mixed with a cellulose solution to adjust the viscosity for optimal deposition. The conversion of the precursor to the CIGS phase was confirmed by X-ray diffraction (XRD). Grain size and morphology were characterised with electron microscopy. A double-layer structure formed during selenization, with a GIGS layer on top of an amorphous carbon layer. Auger electron spectroscopy (AES) shows a decreasing Ga/In ratio from the carbon-CIGS interface towards the CIGS surface. The layer structure grown on Mo-coated glass substrates (conventional dc-sputtering) was processed to solar cells by depositing a US buffer layer (chemical bath deposition) and ZnO/ZnO:Al front contacts (conventional rf-sputtering). A maximum efficiency of 6.7% was achieved with approximately 0.5-mu m-thick absorber layers. Quantum efficiency measurements reveal photon absorption losses for the longer wavelengths, which are attributed to the thin layers. (c) 2004 Elsevier B.V. All rights reserved.
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