期刊
THIN SOLID FILMS
卷 480, 期 -, 页码 419-425出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2004.11.142
关键词
Cu(In,Ga)Se2; CuGaSe2; tandem; bifacial; thin film solar cells; transparent conducting oxides; Ga2O3; ITO; SnO2
The cell performance of the Cu(In1-xGax)Se-2(CIGS) devices fabricated using transparent conducting oxide (TCO) back contacts deteriorated at high absorber deposition temperatures used for conventional CIGS devices with Mo back contacts. Therefore, understanding of the interfacial properties at the GIGS/TCO boundary is one of the most important issues for achieving high efficiency semi-transparent and bifacial devices. It was found that the deterioration in cell performance was due to reduction in the fill factor (FF) originating from the increased resistivity of the TCOs. TEM, EDX, SIMS, and XPS analyses revealed that the increased resistivity was mainly attributable to the removal of fluorine from SnO2:F and the undesirable formation of a Ga2O3 thin layer at the CIGSATO and CIGS/ZnO:Al interfaces. The formation of Ga2O3 was eliminated by inserting thin Mo layer between the ITO and GIGS layers. (c) 2004 Elsevier B.V. All rights reserved.
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