期刊
APPLIED CLAY SCIENCE
卷 48, 期 3, 页码 516-521出版社
ELSEVIER
DOI: 10.1016/j.clay.2010.02.017
关键词
Kaolinite; Functionalization; Hybrid material; Tris(hydroxymethyl)aminomethane; Amino-compound
资金
- Spanish and Brazilian Ministries of Education [PHB2005-0077-PC, CAPES 110/06]
- Junta de Castilla y Leon
- FAPESP
- CNPq
A novel reactive solid containing amine groups was prepared by functionalization of the Brazilian Sao Simao kaolinite with tris(hydroxymethyl)aminomethane, designated IRIS. The functionalization involved refluxing of the molten TRIS in the presence of kaolinite previously intercalated with dimethylsulfoxide (DMSO). IRIS effectively displaced DMSO from the clay mineral interlayer, giving rise to Al-O-C bonds, thereby forming a hybrid organic-inorganic matrix. The resulting material was characterized by X-ray diffraction, thermal analysis, infrared absorption spectroscopy, and C and N elemental analysis. The X-ray diffractograms revealed the intercalation of DMSO, and subsequently TRIS. The thermogravimetric curves of the kaolinite samples functionalized with TRIS indicated that the materials were thermally stable up to 250 degrees C. Displacement of the bands due to interlayer hydroxyl groups in the infrared absorption spectra and the presence of vibration bands due to NH2 groups at 3349, 3331, 3290, and 1589 cm(-1) also confirmed functionalization of the kaolinite with TRIS. (C) 2010 Elsevier B.V. All rights reserved.
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