期刊
COORDINATION CHEMISTRY REVIEWS
卷 249, 期 11-12, 页码 1155-1184出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2004.11.010
关键词
atom transfer radical polymerization; copper(I); copper(II); structures
Structural features of copper(I) and copper(II) complexes with bidentate, tridentate and tetradentate nitrogen based ligands commonly used in atom transfer radical polymerization (ATRP) were extensively reviewed and discussed based on several spectroscopic techniques. Complexing ligands included 2,2'-bipyridine (bpy), 4,4'-di(5-nonyl)-2,2'-bipyridine (dNbpy), NNM,APtetramethylethylenediamine (TMEDA), N-propyl(2-pyridyl)methanimine (NPrPMI), 2,2': 6,2 -terpyri dine (tpy), 4,4',4-tris(5-nonyl)- 2,2':6',2-terpyridine (tNtpy), N,N,N',N'',N'''-pentamethyldiethylenetriamine (PMDETA), N,N-bis(2-pyridylmethyl)octylamine (BPMOA), 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA), tris[2-(dimethylamino)ethyl]amine (Me6TREN), tris[(2-pyridyl)methyl]amine (TPMA) and 1,4,8,1 1-tetraaza-1,4,8,11-tetramethylcyclotetradecane (Me(4)CYCLAM). Additionally, structures of copper(I) and copper(II) complexes with diethylenetriamine (DETA), triethylenetetramine (TETA), N,N-bis(2-pyridylmethyl)amine (BPMA), tris[2-aminoethyl]amine (TREN) and 1,4,8,1 1-tetraazacyclotetradecane (CYCLAM) were discussed. The structures were found to depend on the complexing ligand, solvent and temperature. (c) 2004 Elsevier B.V. All rights reserved.
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