期刊
BIOMATERIALS
卷 26, 期 18, 页码 3819-3830出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biomaterials.2004.10.013
关键词
calcium phosphate bioceramic; silica; ceramic structure; electron spin resonance
Impurity centers associated with silicon have been observed in the phase mixture of silicon substituted apatite (Si-Ap) and silicon stabilized tricalcium phosphate (Si-TCP) using electron spin resonance (ESR). Two unique centers occur upon addition of SiO2 to the calcium phosphate system: an orthorhombic center with g-values 2.0072 +/- 0.0001, 2,0024 +/- 0.0001 and 2.0003 +/- 0.0001 (Si-h1) and a center with tetrahedral symmetry having g-values components 2.0054 +/- 0.0001 and 1.9992 +/- 0.0003 (Si-h2). Both centers are hypothesized to be characteristic of defects associated with silicon in the Si-Ap phase. Through comparison of the intensity of F-OH centers in undoped calcium hydroxyapatite (HA) prepared with various levels of OH occupancy, a relationship is demonstrated between the ESR intensity of an F-center signal with g = 2.0019 + 0.0004 (F-OH) and the OH occupation of HA. Relative changes in the intensity of ESR signals Si-h1 and F-OH are consistent with a chemical model describing the substitution of SiO44- for PO43- in HA,with the creation of OH- vacancies as charge compensation, resulting in a mixed phase composition of Si-Ap and Si-TCP that results when a hydroxyapatite precipitate (HA) is heated in the presence of added SiO2. (C) 2004 Elsevier Ltd. All rights reserved.
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