Assessment of metals in sediments from Lake Macquarie, New South Wales, Australia, using normalisation models and sediment quality guidelines

Industrial activity since the 1890s and, more recently catchment development has resulted in significant metal contamination in Lake Macquarie, an estuary in New South Wales, Australia. This paper presents an analysis of metal concentrations in surface sediments from Lake Macquarie using normalisation models to estimate enrichment relative to natural background concentrations and by comparing concentrations with sediment quality guidelines (SQGs) and effects range median quotients to assess the potential for ecological harm. Of the 12 metals examined, cadmium, lead, mercury, selenium, silver and zinc were enriched in surface sediments throughout the lake. The greatest contamination was found in the north of the lake and, for selenium, also in areas adjacent to two power stations. Comparisons with SQGs and effects range median quotients found that sediments from a site in Cockle Bay had concentrations of metals with the highest likelihood of causing adverse effects on sediment associated biota, and that the likelihood adverse decreased with distance from Cockle Bay. Comparisons with historical sediment quality data indicated that there has been a marked reduction in surface metal concentrations throughout the lake over 15 years. Models could not be constructed for all metals due to low background concentrations. For most metals, simple linear regression models were adequate, but for selenium and arsenic a multiple regression model provided a better estimate of background concentrations. SQGs possibly overestimated effects for arsenic, which has naturally high concentrations in the lake and underestimated the potential for ecological effects in coarser sediments. (C) 2004 Elsevier Ltd. All rights reserved.