期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 239, 期 -, 页码 10-15出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2018.07.072
关键词
Diesel exhaust; NOx Reduction; Soot oxidation; Nitrous oxide; Silver
资金
- RCUK through Environmental programme of the EPSRC UK Catalysis Hub [EP/K014706/1, EP/K014668/1, EP/K014854/1, EP/K014714/1, EP/M013219/1]
- RCUK through Cardiff University EPSRC Impact Acceleration Account
- RCUK through EPSRC Centre for Doctoral Training in Catalysis - EPSRC
- RCUK through EPSRC Centre for Doctoral Training in Catalysis (Cardiff University)
- RCUK through EPSRC Centre for Doctoral Training in Catalysis (University of Bath)
- RCUK through EPSRC Centre for Doctoral Training in Catalysis (University of Bristol)
- EPSRC [1937620, EP/K014854/1] Funding Source: UKRI
One of the outstanding challenges in diesel exhaust catalysis is to integrate oxidation chemistry, soot filtration and NOx reduction in a single aftertreatment unit, while avoiding the need for fuel injection to regenerate the filter. Here we show that destruction of trapped soot can be initiated catalytically at 200 degrees C when its oxidation is coupled with non-selective NOx reduction (using NH3 as reductant), which acts as an in-situ source of N2O. In laboratory tests over an extended temperature range (up to 800 degrees C), using supported silver as a catalyst for both non-selective NOx-reduction and soot oxidation, the conversion of immobilised soot to CO2 can be resolved into four consecutive steps as the temperature rises: catalysed oxidation by N2O; non-catalysed oxidation by NO2; catalysed oxidation by O-2; non-catalysed oxidation by O-2. Initial engine tests indicate that the critical first step (C + N2O) can be replicated in a diesel exhaust.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据