期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 138, 期 -, 页码 199-211出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2013.02.053
关键词
Pt/Al2O3; Sulfates; Diesel soot oxidation; Surface oxygenated complexes; NOx preferential adsorption
资金
- Ministry of Science and Technology of China [2013AA061902, 2010CB732304]
The sulfated Pt/Al2O3 catalyst was synthesized by impregnating H2SO4 on the Pt/Al2O3 catalyst. It exhibits higher catalytic activity than Pt/Al2O3 for soot oxidation under loose contact conditions in a feed flow containing NO and O-2. Further studies ascribe its good activity to a synergistic effect between sulfate species and platinum. Firstly, the electronegative sulfate species may improve the oxidation-resistance of metallic platinum in the oxidizing atmosphere, which is important for achieving high NO <-> NO2 <-> soot recycling efficiency; Secondly, the sulfate species inhibit the NOx adsorption on the alumina support, leading to a preferential adsorption of NOx on the surface of soot rather than on the catalyst, and thus provide more chances for NO2-soot reaction to generate the surface oxygenated complexes (SOCs); Finally, the sulfate species can promote the further decomposition of these SOCs species, resulting in a high catalytic efficiency for soot oxidation. (C) 2013 Elsevier B.V. All rights reserved.
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