A ferromagnetic γ-alumina-supported iron catalyst for CWPO. Application to chlorophenols

A ferromagnetic gamma-Al2O3-supported iron catalyst has been prepared and its activity and stability in catalytic wet peroxide oxidation (CWPO) have been compared with those of a previous iron-based conventional catalyst using the same support. Both catalysts were characterized by nitrogen adsorption-desorption isotherms, ICP, TXRF, XRD, XPS, elemental analysis and Mossbauer spectroscopy. The behavior of these catalysts in CWPO of chlorophenols has been related with the nature of the dominant iron species (magnetite or hematite). The results showed that the magnetic catalyst improved significantly the decomposition of H2O2 leading to an increased degradation and mineralization of chlorophenols. Complete conversion of those target pollutants and more than 75% TOC reduction were achieved after 4h under stoichiometric H2O2 dose, 100 mg L-1 initial chlorophenol concentration, 1 g L-1 catalyst, pH 3 and 50 degrees C temperature. Moreover, complete dechlorination of all the chlorophenols tested was achieved, being the residual organic by-products short-chain acids without significance in terms of ecotoxicity. The catalyst showed a remarkable stability in long-term continuous experiments with limited Fe leaching, below 5% of the initial loading after 100 h on stream. An additional clear advantage of the new catalyst is its easy separation and recovery from the reaction medium by applying an external magnetic field. (C) 2013 Elsevier B.V. All rights reserved.