期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 117, 期 -, 页码 268-274出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2012.01.021
关键词
Photocatalysis; Carbon nanotubes; Carbon nitrides; Hydrogen evolution
资金
- National Science Foundation of China [21003157]
- Beijing Nova Program [2008B76]
- Doctor Foundation of Chinese Ministry of Education [200804251014]
Novel multi-walled carbon nanotubes (MWNTs) and graphitic carbon nitride (g-C3N4) composite photocatalysts were synthesized via a facile heating method. The resulting MWNTs/g-C3N4 composite photocatalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflection spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) spectroscopy. The photoelectrochemical l-t curves were tested using several on-off cycles of visible light irradiation. The visible light photocatalytic hydrogen evolution was investigated for MWNTs/g-C3N4 in methanol aqueous solutions. The optimal MWNTs content is determined to be 2.0 wt%; and corresponding H-2 evolution rate is 7.58 mu mol h(-1), about 3.7 folds that of pure g-C3N4. A possible mechanism of MWNTs on the enhancement of visible light performance is proposed. It suggests that MWNTs play key roles, which may lead to efficiently separation of the photo-generated charge carriers and, consequently, enhance the visible light photocatalytic H-2 production activity. (c) 2012 Elsevier B.V. All rights reserved.
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