期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 117, 期 -, 页码 310-316出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2012.01.029
关键词
Photocatalysis; Titania; Anatase; Iron; Fe; Sulfur; Co-doping; Selective partial oxidation; Toluene; Benzaldehyde
资金
- CICYT [CTQ2010-14872/BQU]
- Marie Curie program [FP7-PEOPLE-2009-IEF-253445]
Iron and sulfur single- and co-doped TiO2 nanocrystals were prepared and characterized by a multitechnique approach. The presence of sulfur affected drastically the crystal size of anatase as well as other morphological characteristics such as BET surface area, pore volume and pore size. Significant differences were also detected on the isolated OH species concentration as a function of sulfur content. On the contrary, X-ray absorption spectroscopy (XAFS) showed that sulfur did not alter substantially the structural and electronic properties of Fe on TiO2. The photocatalytic activity of the synthesized TiO2 powders was studied in the gas-phase oxidation of toluene. The trials showed that the co-doped S/Fe-TiO2 nanomaterials have enhanced photo-activity compared to the reference single-doped Fe-TiO2 under both sunlight and UV-light irradiation. This is not however the case if compared with the single S-doped materials. Sulfur additionally modifies the selectivity of toluene photo-oxidation toward partial oxidation products. The partial vs. total oxidation yield ratio increased with increasing S content in both co-doped S/Fe-TiO2 or single-doped S-TiO2 series and was attributed to differences in surface properties related to both S-containing and OH entities. (c) 2012 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据