Monodisperse polystyrene microspheres prepared by dispersion polymerization with microwave irradiation

Monodisperse polystyrene microspheres with diameters of 200-500 nm were prepared by dispersion polymerization with microwave irradiation with poly (N-vinylpyrrolidone) as a steric stabilizer and 2,2'-azobisisobutyronitrile as a radical initiator in an ethanol/water medium. The morphology, size, and size distribution of the polystyrene microspheres were characterized with transmission electron microscopy and photon correlation spectroscopy, and the formed films of the polystyrene dispersions were characterized with atomic force microscopy. The effects of the monomer concentration, stabilizer concentration, and initiator concentration on the size and size distribution of the polystyrene microspheres were investigated. The polystyrene microspheres prepared by dispersion polymerization with microwave irradiation were smaller, more uniform, and steadier than those obtained with conventional heating. (c) 2005 Wiley Periodicals, Inc.