期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 95, 期 1-2, 页码 110-119出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2009.12.016
关键词
Fe,Al-containing mesoporous mesophase materials; Fe,Al-pillared clay; Hydrogen peroxide; Phenol; Oxidation
资金
- Russian Foundation for Basic Research [08-08-00729-a]
Iron-containing mesoporous mesophase materials Fe,Al-MMM-2 have been synthesized according to a sol-mesophase route under mild acidic conditions (pH 2.3-4.4) using Keggin type cation [FeAl12O4(OH)(24)(H2O)(12)](7+) (FeAl127+) as Al and Fe sources. Effect of pH of the synthetic solution on structural and physicochemical properties of Fe,Al-MMM-2 has been evaluated by means of small- and wide-angle XRD, FTIR, DR-UV-vis, and N-2-adsorption/desorption analysis. It has been established that deviation of stability of FeAl127+ cation at various pH determines Al/Fe ratio in the resulting material as 12/1 (material synthesized at pH 4.4), and 6/1 (pH 2.4 and 3.3). Correlation between incorporation of Al and Fe in different forms and resulting materials texture is discussed. Fe.Al-MMM-2 materials have been tested as catalysts for wet phenol oxidation with H2O2. Insertion of Al species into the framework of the silicate matrix increases the activity comparing to a reference Fe,Al-pillared clay due to both higher surface acidity and lower diffusion limitations that correspond to Fe,Al-MMM-2. (C) 2009 Elsevier B.V. All rights reserved.
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