期刊
ORGANIC LETTERS
卷 7, 期 12, 页码 2389-2392出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol0506516
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资金
- NIGMS NIH HHS [GM073943] Funding Source: Medline
This report describes the solid-phase synthesis of hydrogen-bond surrogate-derived artificial a-helices by a ring-closing metathesis reaction. From a series of metathesis catalysts evaluated for the synthesis of these helices, the Hoveyda-Grubbs catalyst was found to afford high yields of the macrocycle irrespective of the peptide sequence.
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