期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 88, 期 3-4, 页码 525-532出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2008.10.008
关键词
Titania; Fe3+ doped; Au deposited; Photodegradation; Synergistic effect
资金
- Shanghai Pujiang Programme [05PJ14033]
- Shanghai Nanotechnology Promotion Centre [0752/001]
- Nationall Nature Science Foundation of China [20577009, 20773039]
- National Basic Research Program of China (973 Program) [2007CB613306,2004CB719500]
- Ministry of Science and Technology of China [2006AA06Z379, 2006DFA52710]
Fe3+ doped TiO2 deposited with Au (Au/Fe-TiO2) was successfully prepared with an attempt to extend light absorption of TiO2 into the visible region and reduce the rapid recombination of electrons and holes. The samples were characterized by X-ray diffraction (XRD), N-2 physical adsorption, Raman spectroscopy, atomic absorption flame emission spectroscopy (AAS), UV-vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL) spectra. The photocatalytic activities of the samples were evaluated for the degradation of 2,4-chlorophenol in aqueous solutions under visible light (lambda > 420 nm) and UV light irradiation. The results of XRD, XPS and high-resolution transmission electron microscopy (HRTEM) analysis indicated that Fe3+ substituted for Ti3+ in the lattice of TiO2, Au existed as Au-0 on the surface of the photocatalyst and the mean particle size of Au was 8 nm. Diffuse reflectance measurements showed an extension of light absorption into the visible region for Au/Fe-TiO2, and PL analysis indicated that the electron-hole recombination rate has been effectively inhibited when Au deposited on the surface of Fe-doped TiO2, Compared with Fe doped TiO2 sample and Au deposited TiO2 sample, the Au/Fe-TiO2 photocatalyst exhibited excellent visible light and UV light activity and the synergistic effects of Fe3+ and Au was responsible for improving the photocatalytic activity. (C) 2008 Elsevier B.V. All rights reserved.
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