期刊
JOURNAL OF NON-CRYSTALLINE SOLIDS
卷 351, 期 18, 页码 1500-1511出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jnoncrysol.2004.04.028
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An interrelationship between parameters of short and intermediate range order in silicate glasses and the tendency to nucleate homogeneously ill the volume is tested. Changes in the average coordination number and metal-oxygen distance of network modifying cations as well as changes in the concentration of constitutive silica tetrahedra accompanied with the crystallization of 18 stoichiometric glass compositions into their crystalline analogs are determined. The intermediate range structure of the glasses is investigated by configurational entropy and flow birefringence. The changes ill structural parameters are analyzed ill terms of the reduced glass transition temperature T-rg, which is negatively correlated with the maximal rate of volume nucleation. The results indicate that the short-range structure in stoichiometric glasses is, in general, very similar to the corresponding crystal structure but independent of the T-rg-scale and for this reason independent of nucleation properties. In contrast to the short range of the glass structure, birefringence induced by a forced flow above the glass transition temperature and configurational entropy are positively correlated with increasing T-rg. The results indicate increased structural order in the intermediate range for melts with a high supercool limit (T-rg < 0.58). It is concluded that this order phenomena may promote nucleation events and may help to explain the tendency to volume nucleation of silicate glasses with T-rg < 0.58. (c) 2005 Elsevier B.V. All rights reserved.
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