期刊
BIOSENSORS & BIOELECTRONICS
卷 20, 期 12, 页码 2517-2554出版社
ELSEVIER ADVANCED TECHNOLOGY
DOI: 10.1016/j.bios.2004.10.003
关键词
ascorbate oxidase; azurin; bilirubin oxidase; ceruloplasmin; direct electron transfer; galactose oxidase; gold electrode; graphite electrode; hemocyanin; laccase; redox potential; T1, T2 and T3 sites; tyrosinase
类别
资金
- NIGMS NIH HHS [GM 46749] Funding Source: Medline
The electrochemistry of some copper-containing proteins and enzymes, viz. azurin, galactose oxidase, tyrosinase (catechol oxidase), and the blue multicopper oxidases (ascorbate oxidase, bilirubin oxidase, ceruloplasmin, laccase) is reviewed and discussed in conjunction with their basic biochemical and structural characteristics. It is shown that long-range electron transfer between these enzymes and electrodes can be established, and the mechanistic schemes of the DET processes are proposed. (c) 2004 Elsevier B. V. All rights reserved.
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