4.8 Article

Scanning tunneling microscopy experiments on single molecular landers

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NATL ACAD SCIENCES
DOI: 10.1073/pnas.0500915102

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contact; molecular wire; nanoelectrodes; single-molecule manipulation

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Molecular landers are molecules comprising of a central rigid molecular wire maintained above a metallic surface by organic spacers, which allows specific ultrahigh vacuum-scanning tunneling microscopy experiments to be performed at the single-molecule level. The understanding of the molecule-surface interactions, intramolecular mechanics, and the possibility to perform extremely precise tipinduced manipulation permit these molecules to be brought in contact with a nanoelectrode and the resulting electronic interaction to be analyzed in well controlled conditions.

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