期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 109, 期 24, 页码 11880-11885出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp044651j
关键词
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Although it is well-known that TiO2 incorporation can greatly improve the cyclic stability of V2O5, the influences of TiO2 addition on the Li+ intercalation properties of V2O5 remain an issue of debate in literature. In this paper, we report on a systematic investigation of the preparation and intercalation properties of V2O5-TiO2 mixture films. The present work demonstrates that high Li+ intercalation rates and capacity in V2O5 films are achievable with TiO2 addition. For example. the addition of 20 mol %, Ti into V2O5 polycrystalline demonstrated an approximated 100%, improvement in Li+ intercalation Performance as compared to single V2O5 electrodes. Such enhancement in intercalation properties of V2O5 films with TiO2 addition was attributed to changes in microstructure, crystallinity, and also a possible lattice structure and interaction force between adjacent layers in V2O5.
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