An operationally simple and mild protocol for the catalytic enantioselective epoxiclation of alpha,beta-unsaturated ketones has been estabilished using commercially available a,a-diphenyl-L-prolinol as bifunctional organocatalyst and tert-butyl hydroperoxide (TBHP) as oxidant. The epoxides have been obtained in good yields and with up to 80% ee.
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