期刊
TETRAHEDRON
卷 61, 期 26, 页码 6276-6282出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.03.104
关键词
[3+2] cycloaddition; organocatalysis; phosphine; pyrrolines
Tributylphosphine was used as catalyst to facilitate a [3+2] cycloaddition between gamma-substituted allenoates and N-sulfonylimines. The resulting adducts, 3-carbethoxy-2,5-disubstituted-3-pyrrolines were formed in excellent yields with high diastereoselectivity. The reaction went to completion in several hours at room temperature, and the starting materials were easily prepared with one step from commercially available compounds via known procedures. (c) 2005 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据