期刊
TETRAHEDRON
卷 61, 期 26, 页码 6386-6408出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.03.122
关键词
chiral sulfinamide; chiral sulfoxide; 1,2,3-oxathiazolidine-2-oxide
A simple, general, and practical technology to prepare enantiopure 1,2,3-oxathiazolidine-2-oxide derivatives using chiral aryl N-suifonyl aminoalcohol derivatives and thionyl chloride is reported. The versatility of these novel chiral building blocks (MIOO and TMPOC), was exernplified by the expedient production of a variety of unique chiral suifoxides and valuable chiral sultinamides in excellent yields and enantiopurities. (c) 2005 Elsevier Ltd. All rights reserved.
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