期刊
TETRAHEDRON
卷 61, 期 26, 页码 6315-6329出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.03.107
关键词
cross-coupling; hypophosphorous; alkoxysilane; palladium
The direct formation of H-arylphosphinates and related compounds can be accomplished using palladium catalysis. This full paper examines the scope and sonic mechanistic aspects of this phosphorus-carbon bond forming reaction. The reactions of alkenyl and allylic halides are also described for the first time. This novel cross-coupling provides a convenient access to a variety of substituted H-phosphinates. (c) 2005 Elsevier Ltd. All rights reserved.
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