期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 127, 期 25, 页码 9260-9266出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja051875m
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The copper-catalyzed reaction of isocyanides (CNCH(2)EWG(1)) 1 with electron-deficient alkynes (RC equivalent to CEWG(2)) 2 gave the 2,4-di-EWG-substituted pyrroles 3 selectively, whereas the phosphine-catalyzed reaction of 1 with 2 afforded the 2,3-di-EWG-subsituted pyrroles 4. Accordingly, regioselective synthesis of substituted pyrroles has been achieved by merely choosing the catalyst.
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