期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 127, 期 25, 页码 9079-9084出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja050909n
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资金
- NIGMS NIH HHS [GM070181-01A1] Funding Source: Medline
The synthesis and characterization of a series of primary and secondary alcohol adducts of 1,3-dimesitylimidazolin-2-ylidene is described. These adducts are stable as solids at room temperature, but readily release alcohol and the free carbene in solution. These alcohol adducts function as excellent single-component catalyst/initiators for the ring-opening polymerization of lactide under mild conditions, providing polymers with controlled molecular weights and narrow polydispersities. Multifunctional adducts were used to prepare poly(lactide)s of more complex architectures.
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