期刊
APPLIED CATALYSIS A-GENERAL
卷 467, 期 -, 页码 91-97出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2013.07.011
关键词
Isobutene; Bio-ethanol; Mixed oxide; Acid-base
资金
- Archer Daniels Midland (ADM) Company
- US Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences
- DOE's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL)
ZnxZryOz mixed oxides were studied for direct conversion of ethanol to isobutene. Reaction conditions (temperature, residence time, ethanol molar fraction, steam to carbon ratio), catalyst composition, and pretreatment conditions were investigated, aiming at high-yield production of isobutene under industrially relevant conditions. An isobutene yield of 79% was achieved with an ethanol molar fraction of 8.3% at 475 degrees C on fresh Zn1Zr8O17 catalysts. Further durability and regeneration tests revealed that the catalyst exhibited very slow deactivation via coking formation with isobutene yield maintained above 75% for more than 10 h time-on-stream. More importantly, the catalysts activity in terms of isobutene yield can be readily recovered after in situ calcination in air at 550 degrees C for 2.5 h. XRD, TPO, IR analysis of adsorbed pyridine (IR-Py), and nitrogen sorption have been used to characterize the surface physical/chemical properties to correlate the structure and performance of the catalysts. (C) 2013 Elsevier B.V. All rights reserved.
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