期刊
APPLIED CATALYSIS A-GENERAL
卷 468, 期 -, 页码 327-333出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2013.09.008
关键词
AACH; Hydrodesulfurization catalyst; Structural features; Physicochemical properties; Catalytic performance
资金
- Fundamental Research Funds for the Central Universities [13CX06052A]
In this paper, a precursor ammonium aluminum carbonate hydroxide (AACH) was synthesized by a low-temperature solid-state reaction, then alumina labeled as Al2O3-AC was obtained by the calcination of AACH, and finally, catalyst labeled as NiMo/Al2O3-AC supported on Al2O3-AC was prepared using the method of incipient wetness impregnation. The properties of both support and catalyst were investigated by a series of characterization methods. The results indicated that Al2O3-AC had unique bimodal porous structure, high acid content and five-fold coordinated aluminum (AlO5) on the surface. Moreover, NiMo/Al2O3-AC exhibited uniform dispersion of active components, higher Bronsted acid sites concentration and weaker metal-support interaction. Encouraged by those excellent properties of Al2O3-AC and NiMo/Al2O3-AC, the catalyst NiMo/Al2O3-AC was evaluated in the hydrodesulfurization (HDS) of dibenzothiophene (DBT), showing high conversion ratio of DBT. (C) 2013 Elsevier B.V. All rights reserved.
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