期刊
CRYSTAL GROWTH & DESIGN
卷 5, 期 4, 页码 1317-1319出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg050051d
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Crystalline hexagonal-shaped superstructures of calcium carbonate, synthesized in the presence of ammonia, are shown to be assembled by a three-dimensional oriented attachment of vaterite nanoparticles. This unusual crystallographic lock-in mechanism enables the formation of complicated rounded structures with a crystallographic orientation from nanosized building blocks, which has so far only been found for transition metal systems.
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