期刊
APPLIED CATALYSIS A-GENERAL
卷 378, 期 2, 页码 187-194出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2010.02.018
关键词
Catalytic partial oxidation; Methane; Thermography; Hot spot; Rhodium; Base metal: alloy
资金
- Japan Oil, Gas and Metals National Corporation (JOGMEC)
- Chiyoda Corporation
- World Premier International Research Center (WPI) Initiative on Materials Nanoarchitectonics, MEXT
Modifying effects of Fe, Co or Ni over 1 wt% Rh/MgO on the catalytic performance in the catalytic partial oxidation (CPO) of methane were investigated. The optimization of the additive amount was determined by the results of the activity test in the CPO of methane with N-2 dilution. The optimum amount of Co (Co/Rh = 1) or Ni (Ni/Rh =1.5) addition to Rh/MgO enhanced the CH4 conversion and selectivities to H-2 and CO, in contrast, the addition of Fe to Rh/MgO decreased the properties. The results of H-2 titration and H-2 adsorption on the catalysts quenched from the CPO reaction conditions indicate that the RhCo/MgO gave low oxidation degree during the CPO of methane and high resistance to the oxidation was demonstrated. In the CPO of methane without N-2 dilution, Rh-Co/MgO (Co/Rh = 1) had much lower catalyst bed temperatures than other catalysts, and it can suppress the hot spot formation. This property is also related to the high resistance to the oxidation. The catalyst surface is maintained in a reduced state even in the presence of oxygen enables the overlap of the exothermic oxidation zone with endothermic reforming zone and can decrease the bed temperature remarkably. (C) 2010 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据