期刊
APPLIED CATALYSIS A-GENERAL
卷 355, 期 1-2, 页码 100-108出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2008.12.001
关键词
Deoxygenation; Fatty acid; Palladium
资金
- Abo Akademi Process Chemistry Centre of Excellence Programmes (2000-2011)
- Academy of Finland
- DGAPA-PAPIIT (UNAM, Mexico) [N 120706-3]
- RFBR [07-03-12159]
Catalytic deoxygenation of palmitic and stearic acids mixture was studied over four synthesized Pd catalysts supported on synthetic carbon (Sibunit) in a semibatch reactor and dodecane as a solvent at 260-300 degrees C. The catalysts were prepared by precipitation deposition method using Pd chlorides as metal precursors. All catalysts contained 1 wt.% Pd, however, the metal dispersion was systematically varied. An optimum metal dispersion giving the highest reaction rate was observed. The main liquid phase products were n-heptadecane and n-pentadecane, which were formed in parallel. In addition to the particle size effect the impact of mass transfer was elucidated and a detail discussion on temperature programmed desorption of CO from the fresh and spent samples was provided. (C) 2008 Elsevier B.V. All rights reserved.
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