期刊
APPLIED CATALYSIS A-GENERAL
卷 360, 期 2, 页码 145-153出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2009.03.016
关键词
Styrenes; Vinylation; Heterogeneous palladium catalyst; Potassium vinyltrifluoroborate; Suzuki-Miyaura cross-coupling
资金
- CNRS
- Ministere de I'Education Nationale, de I'Enseignement Superieur et de la Recherche
- Programme interdisciplinaire: Chimie Pour le Developpement Durable - Reseau de Recherche 2: Aller vers une Chimie Ecocompatible
Heterogeneous Pd/C catalyst was applied to the Suzuki-Miyaura vinylation of various aryl and heteroaryl halides under aerobic and mild reaction conditions [1.0 mmol aryl halide, 1.5 mmol potassium vinyltrifluoroborate, 3.0 mmol K3PO4 center dot H2O, 0.1 mol% Pd/C-(EVO), 1 mL NMP, 100 degrees C, 24 h]. Useful isolated yields (57-73%) were achieved. In some cases, the catalytic system should be tuned to face the reactivity of the aryl halides: while 0.1 mol% Pd/C is sufficient for almost all aryl bromides, 1.0 mol% Pd/C was used for free phenols. The heterogeneous catalyst was proved to be stable upon several catalytic cycles: however, the results showed that this was dependent on addition of the base. Hot-filtration experiment indicates that the activity was mainly due to leached Pd-species, indicating that the Pd/C catalyst acts as a palladium reservoir. (c) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据