期刊
APPLIED CATALYSIS A-GENERAL
卷 341, 期 1-2, 页码 50-57出版社
ELSEVIER
DOI: 10.1016/j.apcata.2007.12.022
关键词
epoxidation of cyclohexene; hydrotalcites and mixed oxides catalysts; memory effect
The epoxidation of cyclohexene by hydrogene peroxide and benzonitrile, in methanol as solvent on solid base catalysts, hydrotalcites (HT) and corresponding mixed oxides (C-HT) was investigated. The employed catalysts were as-synthesized Mg/Al; Mg,Zn/Al; Mg/Ga,Al hydrotalcites, their derived mixed oxides and the corresponding reconstructed hydrotalcite forms (R-HT) obtained via the memory effect upon a rehydration treatment of C-HT. The catalysts were characterized by XRD, CO2-TPD and N-2 adsorption-desorption measurements. The reconstructed HT samples exhibit higher activity in comparison to the as-synthesized carbonated HT samples. A tentative correlation of the catalytic properties with the base strength of the active sites, the structural and textural characteristics of the catalysts, has been explored. (c) 2008 Published by Elsevier B.V.
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